The flow characteristics of falling film of amino acid ionic liquid (AAIL) aqueous solution on a uniformly heated vertical plane have been experimentally studied. The infrared images and temperature profiles have been determined and used to analyze the fluid flow. It is proven that the Marangoni effect exists widely and has significant influence on the flow region of falling film. A novel flow pattern is additionally observed when the mass fraction of AAIL is 30%. The flow patterns are also shown to be affected by the wall-liquid temperature differential, the flow rate and the concentration of solute. The experimental results of AAIL falling film are expected to be helpful for the further industrial application of ionic liquids.

References

1.
Brennecke
,
J. F.
, and
Maginn
,
E. J.
, 2001, “
Ionic Liquids: Innovative Fluids for Chemical Processing
,”
AIChE J.
,
41
, pp.
2384
2389
.
2.
Bates
,
E. D.
,
Mayton
,
R.
,
Ntai
,
I.
, and
Davis
,
J. H. J.
, 2002, “
CO2 Capture by a Task-Specific Ionic Liquid
,”
J. Am. Chem. Soc.
,
124
(
6
), pp.
926
927
.
3.
Cadena
,
C.
,
Anthony
,
J. L.
,
Shah
,
J. K.
,
Morrow
,
T. I.
,
Brennecke
,
J. F.
, and
Maginn
,
E. J.
, 2004, “
Why Is CO2 So Soluble in Imidazolium-Based Ionic Liquids?
,”
J. Am. Chem. Soc.
,
126
, pp.
5300
5308
.
4.
Jiang
,
Y. Y.
,
Zhou
,
Z.
,
Jiao
,
Z.
,
Li
,
L.
,
Wu
,
Y. T.
, and
Zhang
,
Z. B.
, 2007, “
SO2 Gas Separation Using Supported Ionic Liquid Membranes
,”
J. Phys. Chem. B
,
111
(
19
), pp.
5058
5061
.
5.
Jiang
,
Y. Y.
,
Wang
,
G. N.
,
Zhou
,
Z.
,
Wu
,
Y. T.
,
Geng
,
J.
, and
Zhang
,
Z. B.
, 2008, “
Tetraalkylammonium Amino Acids as Functionalized Ionic Liquids of Low Viscosity
,”
Chem. Commun.
,
4
, pp.
505
507
.
6.
Zhang
,
F.
,
Fang
,
C. G.
,
Wu
,
Y. T.
,
Li
,
A. M.
, and
Zhang
,
Z. B.
, 2010, “
Absorption of CO2 in the Aqueous Solutions of Functionalized Ionic Liquids and MDEA
,”
Chem. Eng. J.
,
160
(
2
), pp.
691
697
.
7.
Joo
,
S. W.
,
Davis
,
S. H.
, and
Bankoff
,
S. G.
, 1996, “
A Mechanism for Rivulet Formation in Heated Films
,”
J. Fluid Mech.
,
321
, pp.
279
298
.
8.
Kabov
,
O. A.
,
Marchuk
,
I. V.
, and
Chupin
,
V. M.
, 1996, “
Thermal Imaging Study of the Liquid Film Flowing on Vertical Surface With Local Heat Source
,”
Russ. J. Eng. Thermophys.
,
6
(
2
), pp.
105
138
.
9.
Oran
,
A.
,
Davis
,
S. H.
, and
Bankoff
,
S. G.
, 1997, “
Long-Scale Evolution of Thin Liquid Films
,”
Rev. Mod. Phys.
,
69
(
3
), pp.
931
980
.
10.
Schatz
,
M. F.
, and
Neitzel
,
G. P.
, 2001, “
Experiments on Thermocapillary Instabilities
,”
Annu. Rev. Fluid Mech.
,
33
(
1
), pp.
93
127
.
11.
Zaitsev
,
D. V.
, and
Kabov
,
O. A.
, 2005, “
Study the Thermocapillary Effect on a Wavy Falling Film Using a Fiber Optical Thickness Probe
,”
Exp. Fluids
,
36
, pp.
712
721
.
12.
Wu
,
X. Y.
,
Li
,
W.
, and
Luo
,
Z.
, 2011, “
Falling Water Film Evaporation on Horizontal Finned Tube Arrays at Low Pressure
,” ASME, New York, p.
T10239
.
13.
Rahman
,
M. A.
, and
Saghir
,
M. Z.
, 2011, “
Marangoni Convection in Water Isopropanol Mixture in the Presence of Soret Effect
,” ASME, New York, p.
T10030
.
14.
Li
,
Y.
,
Yan
,
J. J.
,
Wang
,
J. S.
, and
Wang
,
G. X.
, 2011, “
A Semi-Empirical Model for Condensation Heat Transfer Coefficient of Mixed Ethanol-Water Vapors
,”
ASME J. Heat Transfer
,
133
(
6
), p.
061501
.
15.
Zhang
,
F.
,
Zhao
,
X. G.
,
Wu
,
Y. T.
,
Wang
,
Z. X.
, and
Zhang
,
Z. B.
, 2008, “
Characterization of Marangoni Effect in Non-Isothermal Falling Liquid Films of Binary Mixtures
,”
Int. J. Therm. Sci.
,
47
(
11
), pp.
1454
1463
.
You do not currently have access to this content.