Anode supported solid oxide fuel cells (SOFC) were fabricated by addition of various metal oxides such as Fe2O3, Co3O4 and TiO2 to thin anode functional layers between the electrolyte (yttria-stabilized zirconia, YSZ) and electrode materials (anode support: YSZ-NiO). Effect of the additives on the power density and impedance spectra of SOFC was studied. It was found that addition of Co3O4 to anode functional layer was most effective towards improvement of power densities and reduction of the total ohmic resistance as well as the area specific resistance of the cells, while addition of TiO2 to anode functional layer resulted in lower power densities. Possible mechanisms on the relationship between the additives in electrode functional layers and the cell performance were briefly discussed.

References

1.
Minh
,
N. Q.
, 1993,
“Ceramic Fuel Cells,”
J. Am. Ceram. Soc.
76
(
3
), pp.
563
88
.
2.
Singhal
,
S. C.
and
Kendall
,
K.
2004,
High Temperature Solid Oxide Fuel Cells,
Elsevier
,
New York
.
3.
Ji
,
Y.
,
Huang
,
Y.-H.
,
Ying
,
J.-R.
, and
Goodenough
,
J. B.
, 2007, “Electrochemical Performance of La-Doped Sr2MgMoO6-δ in Natural Gas,”
Electrochem. Commun.
9
, pp.
1881
1885
.
4.
Zhao
,
F.
, and
Virkar
,
A. V.
, 2005, “Dependence of Polarization in Anode Supported Solid Oxide Fuel Cells on Various Parameters,”
J. Power Sources
,
141
, pp.
79
95
.
5.
Park
,
H.-C.
and
Virkar
,
A. V.
, 2009, “Bimetallic (Ni-Fe) Anode-Supported Solid Oxide Fuel Cells With Gadolinia-Doped Electrolyte,”
J. Power Sources
,
186
, pp.
133
137
.
6.
Zhao
,
F.
,
Armstrong
,
T. J.
and
Virkar
,
A. V.
, 2003, “Measurement of O2-N2 Effective Diffusivity in Porous Media at High Temperature Using an Electrochemical Cell,”
J. Electrochem. Soc.
,
150
(
3
), pp.
A249
A256
.
7.
Gross
,
M. D.
,
Vohs
,
J. M.
, and
Gorte
,
R. J.
, 2007, “An Examination of SOFC Anode Functional Layers Based on Ceria in YSZ,”
J. Electrochem. Soc.
,
154
(
7
), pp.
B694
B699
.
8.
Ishihara
,
T.
,
Yan
,
J.
,
Shinagawa
,
M.
and
Matsumoto
,
H.
, 2006, “Ni-Fe Bimetallic Anode as an Active Anode for Intermediate Temperature SOFC Using LaGaO3 Based Electrolyte Film,”
Electrochim. Acta.
,
52
, pp.
1645
1650
.
9.
Skarmoutsos
,
D.
,
Tietz
,
F.
, and
Nikolopoulos
,
P.
, 2007, “Structure-Property Relationships of Ni/YSZ and Ni/(YSZ+TiO2) Cermets,"
Fuel Cells
,
1
(
3-4
), pp.
243
248
.
10.
Grgicak
,
C. M.
,
Green
,
R. G.
, and
Giorgi
,
J. B.
, 2006, “Control of Microstructure, Sinterability and Performance in Co-Precipitated NiYSZ, CuYSZ and CoYSZ SOFC Anodes,”
J. Mater Chem.
16
, pp.
885
897
.
11.
Kim
,
J.-W.
,
Virkar
,
A. V.
,
Fung
,
K.-Z.
,
Mehta
,
K.
, and
Singhal
,
S. C.
, 1999, “Polarization Effects in Intermediate Temperature, Anode Supported Solid Oxide Fuel Cells,”
J. Electrochem. Soc.
,
146
(
1
), pp.
69
78
.
12.
Holtappels
,
P.
,
Bradley
,
J.
,
Irvine
,
J. T. S.
, and
Mogensen
,
M.
, 2001, “Electrochemical Characterization of Ceramic SOFC Anodes,”
J. Electrochem. Soc.
148
(
8
), pp.
A923
A929
.
13.
Cooper
,
K. R.
and
Smith
,
M.
, 2006, “Electrical Test Methods for Online Fuel Cell Ohmic Resistance Measurement,”
J. Power Sources
,
160
, pp.
1088
1095
.
14.
Bak
,
T.
,
Nowotny
,
J.
,
Rekas
,
M.
, and
Sorrell
,
C. C.
, 2003,
“Defect Chemistry and Semiconducting Properties of Titanium Dioxide: I. Intrinsic Electronic Equilibrium,”
J. Phys. Chem. Solids
,
64
, pp.
1043
1056
.
You do not currently have access to this content.